PFFC - February 2008 - (Page 14) PROCESS MANAGEMENT ������������ ���������� ������������ ���������������� ������� ����������� Drying—Part 1: Liquid Inks ����������������������� ������������ I By David Argent Contributing Editor ������������ ������������ �������������� ���������� � �� �� � �� Process improvement expert David Argent has 30+ years of experience in process analysis with�particular �emphasis on ink and coating design and performance. Contact him at 636-391-8180; djvargent@sbcglobal.net. 14 FEBRUARY 2008 | ����������������� n the next three columns, we will cover the ���������� ������������������� Solvent-Based Inks basic mechanisms of ink drying. This month we look at inks drying primarily by evapora���������������� tion and absorption as related to gravure and ������������ ������������ ���������� flexo printing. ����������� ����������� 1 | Solvent-Based Inks | The fast solvent release and strong adhesion of solvent inks make them ide�������������������� ally suited to printing on nonabsorbent surfaces, and they are the primary ink type for this market segment. On absorbent substrates solvent-based inks dry by a combination of penetration of the ink ������������������� into the substrate and evaporation of the ink solvent from the ink film. Normally, there is no chem��������������������� ical interaction with the substrate. Solvent inks are ������������ ������������������������������� ������������ ���������� very resoluble, and for this reason, they are often ����������������������� favored in gravure printing of paper and board due to lower tendency to plug the image cells. ���������������� 2 | Water-Based Inks | These inks are based on ������������ ��������� ����������� �������� ������� a combination of acidic resin held in solution by ����������� amine and water-borne resin dispersions known as ������������������������������ emulsions. Solution resins aid print quality, and the emulsion is used to provide resistance properties in ����������������������� Water-Based Inks ���������������������� ����������������������������� the dried ink. During drying, several mechanisms �������������������� ���������������������� are happening at the same time. On absorbent ������������������� ������������ surfaces such as paper and board, the ink com������������ ����������������� ponents will start to penetrate into the substrate. ���������� Evaporation of water and amine takes place at the ������������ ������������ same time, often aided by dryers on the press. ���������� ���������������� ������������������� Loss of the liquid part of the binder due to �������������� evaporation and penetration has several effects. The ����������� �� �� �������������������� �� ����������� �� �� ink starts to gel. The acid resin starts to precipitate due to amine removal. The rate of drying depends ������������������ on the absorbency of the substrate. Acid substrate Water-based flexo inks ideally are suited for print������������ components can help set the ink resin by neutraling on paper and board and dominate this segment. ���������� izing the amine and precipitating the soluble ink Water-based inks do not dry or adhere as well to resin. On absorbent stocks the combination of pre- nonabsorbent surfaces. The primary reason is that ������������������� ���������������� ��������������������� cipitation and coalescence produces a drying rate there is no absorbency factor to assist the drying. ������������������������������� often as fast as that of solvent-based inks. So������������������������� these substrates are printed more frequently with ����������������������� ������������������������� Formulation of water-based inks requires a balsolvent-based inks. ������������ ������������ ance of ingredients that are often in conflict. A Due to���������� loss of volatile components in liquid inks more fugitive amine assists drying speed, but print during drying, the dry ink film always is substantially ������������ ��������� quality suffers. Loss of amine in low-coverage thinner than the wet ink film. Factors that in����������� ���������������� �������� decks leads to ink bodying and print decrease drying speed include the use of more ������� fects, but monitoring and maintaining volatile ink components, increased web ������������������������������ ����������� pH in the specified range will keep temperature, and higher air velocity the ink in balance. in the dryers. Not so obvious is that ���������������������� ����������������������������� In many cases, such as corrustronger �������������������� inks dry more quickly due ���������������������� gated box printing, the presses are to metering of a thinner ink film to MORE ON DRYING achieve a specific color. not equipped with dryers. Due to LIQUID INKS �������������������month this column will expenetration of the binder, there is a Next Part 2 of 2 positive mechanical anchor of ink to plore some of these factors in a comsubstrate, providing strong adhesion. puter simulation. ������������������� ������������ COMING NEXT MONTH ������������ ���������� �������������������� ������������������ WWW.PFFC-ONLINE.COM http://WWW.PFFC-ONLINE.COM
Table of Contents Feed for the Digital Edition of PFFC - February 2008 PFFC - February 2008 Contents First Glance Calendar of Events From the Editor Web Lines Process Management News Clips Narrow Web & Label Reporter Narrow Web & Label What’s New Products Carton & Box Reporter Offset Printing A Triple Ply: Coating & Laminating Global Market Is Strong for Vacuum-Coated Products Melamine Innovation: A New Choice for Barrier Coatings How To Optimize Your Coating Solution’s Properties What’s New Products Contract Services Directory Custom Marketplace What’s New Products Services Directory Classified Marketplace Advertisers Index Experience Speaks PFFC - February 2008 PFFC - February 2008 - PFFC - February 2008 (Page Cover1) PFFC - February 2008 - PFFC - February 2008 (Page Cover2) PFFC - February 2008 - PFFC - February 2008 (Page 1) PFFC - February 2008 - Contents (Page 2) PFFC - February 2008 - Contents (Page 3) PFFC - February 2008 - First Glance (Page 4) PFFC - February 2008 - First Glance (Page 5) PFFC - February 2008 - First Glance (Page Insert1) PFFC - February 2008 - First Glance (Page Insert2) PFFC - February 2008 - First Glance (Page 6) PFFC - February 2008 - First Glance (Page 7) PFFC - February 2008 - Calendar of Events (Page 8) PFFC - February 2008 - Calendar of Events (Page 9) PFFC - February 2008 - From the Editor (Page 10) PFFC - February 2008 - From the Editor (Page 11) PFFC - February 2008 - Web Lines (Page 12) PFFC - February 2008 - Web Lines (Page 13) PFFC - February 2008 - Process Management (Page 14) PFFC - February 2008 - Process Management (Page 15) PFFC - February 2008 - News Clips (Page 16) PFFC - February 2008 - News Clips (Page 17) PFFC - February 2008 - News Clips (Page 18) PFFC - February 2008 - Narrow Web & Label What’s New Products (Page 19) PFFC - February 2008 - Narrow Web & Label What’s New Products (Page 20) PFFC - February 2008 - Carton & Box Reporter (Page 21) PFFC - February 2008 - Offset Printing (Page 22) PFFC - February 2008 - Offset Printing (Page 23) PFFC - February 2008 - Offset Printing (Page 24) PFFC - February 2008 - Offset Printing (Page 25) PFFC - February 2008 - A Triple Ply: Coating & Laminating (Page 26) PFFC - February 2008 - A Triple Ply: Coating & Laminating (Page 27) PFFC - February 2008 - A Triple Ply: Coating & Laminating (Page 28) PFFC - February 2008 - A Triple Ply: Coating & Laminating (Page 29) PFFC - February 2008 - Global Market Is Strong for Vacuum-Coated Products (Page 30) PFFC - February 2008 - Global Market Is Strong for Vacuum-Coated Products (Page 31) PFFC - February 2008 - Global Market Is Strong for Vacuum-Coated Products (Page 32) PFFC - February 2008 - Melamine Innovation: A New Choice for Barrier Coatings (Page 33) PFFC - February 2008 - Melamine Innovation: A New Choice for Barrier Coatings (Page 34) PFFC - February 2008 - Melamine Innovation: A New Choice for Barrier Coatings (Page 35) PFFC - February 2008 - How To Optimize Your Coating Solution’s Properties (Page 36) PFFC - February 2008 - How To Optimize Your Coating Solution’s Properties (Page 37) PFFC - February 2008 - How To Optimize Your Coating Solution’s Properties (Page 38) PFFC - February 2008 - How To Optimize Your Coating Solution’s Properties (Page 39) PFFC - February 2008 - How To Optimize Your Coating Solution’s Properties (Page 40) PFFC - February 2008 - How To Optimize Your Coating Solution’s Properties (Page 41) PFFC - February 2008 - How To Optimize Your Coating Solution’s Properties (Page 42) PFFC - February 2008 - What’s New Products (Page 43) PFFC - February 2008 - What’s New Products (Page 44) PFFC - February 2008 - What’s New Products (Page 45) PFFC - February 2008 - What’s New Products (Page 46) PFFC - February 2008 - What’s New Products (Page 47) PFFC - February 2008 - Contract Services Directory (Page 48) PFFC - February 2008 - Contract Services Directory (Page 49) PFFC - February 2008 - Contract Services Directory (Page 50) PFFC - February 2008 - Contract Services Directory (Page 51) PFFC - February 2008 - Custom Marketplace (Page 52) PFFC - February 2008 - Custom Marketplace (Page 53) PFFC - February 2008 - What’s New Products (Page 54) PFFC - February 2008 - What’s New Products (Page 55) PFFC - February 2008 - What’s New Products (Page 56) PFFC - February 2008 - What’s New Products (Page 57) PFFC - February 2008 - What’s New Products (Page 58) PFFC - February 2008 - What’s New Products (Page 59) PFFC - February 2008 - What’s New Products (Page 60) PFFC - February 2008 - What’s New Products (Page 61) PFFC - February 2008 - Services Directory (Page 62) PFFC - February 2008 - Services Directory (Page 63) PFFC - February 2008 - Services Directory (Page 64) PFFC - February 2008 - Classified Marketplace (Page 65) PFFC - February 2008 - Classified Marketplace (Page 66) PFFC - February 2008 - Classified Marketplace (Page 67) PFFC - February 2008 - Classified Marketplace (Page 68) PFFC - February 2008 - Classified Marketplace (Page 69) PFFC - February 2008 - Advertisers Index (Page 70) PFFC - February 2008 - Advertisers Index (Page 71) PFFC - February 2008 - Experience Speaks (Page 72) PFFC - February 2008 - Experience Speaks (Page Cover3) PFFC - February 2008 - Experience Speaks (Page Cover4)
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