Circuits Assembly - March 2008 - (Page 62) Wave Soldering Soldering Atmosphere’s Impact on Solder Joint Formation A Flextronics-Vitronics study finds the delivery method’s impact is minimal. he 2007 iNEMI Roadmap identifies an increase in the use of nitrogen in reflow and wave soldering processes because of the lower wetting forces of Pb-free solders. While flux chemistries are being developed and improved to promote wetting of Pb-free alloys, it will take many iterations and time to achieve the desired results. The iNEMI Roadmap emphasizes nitrogen consumption reductions through alternative low-volume distribution methods. In combination with advanced flux chemistries, this would yield the desired quality and reduce operation costs. To provide clarity to this industry gap, Flextronics and Vitronics Soltec jointly investigated soldering atmosphere’s impact on assembly yields. The question of immediate importance is what purity level and delivery method can be employed without degrading solder joint yield. To address this, the investigation defined two gas delivery techniques at five selected atmospheres specified by the O2 ppm level for reflow assembly of a test PCB. The two nitrogen delivery methods studied were distribution of nitrogen source gas only in the reflow zones, reflow only (RO), and distribution of nitrogen source gas throughout the length of the heated and cooled tunnel, full tunnel (FT). The atmosphere purity for both delivery methods was initiated at a low of 25 ppm (O2) and then increased to 500 ppm, 750 ppm, 1200 ppm and 2500 ppm before concluding in air atmosphere. Yield was determined by quantitatively characterizing the solder’s ability to completely fill vias during a subsequent wave process. The assembly matrix consisted of exposing the boards to two Pb-free reflow processes at each of the defined purity levels and distribution methods. The rationale for specifying hole fill as the limiting quality factor was to identify and expose PCB material and pad finish to the worst possible soldering conditions. Characterization of the assemblies and respective through-hole penetration was performed by measuring the solder rise with an Agilent 5DX programmed to take measurements at each 10% of the via from 100% to 20%. The 16-layer, 0.125"-thick test PCB was FR-4 (Tg of 170°C, Td of 350°C) with Entek Plus HT copper OSP pads. The surface finish was selected for its high industry use and sensitivity or degradation when exposed to elevated temperatures and varying oxygen environments. All through-hole components used in the assembly were rated for Pb-free processing and had Pb-free finish. The components included three 64-pin connectors with gold finish, three plastic dual-inline packages (DIP) with 16 Circuits Assembly MARCH 2008 T 1.0 0.9 0.8 Wave Solder Ambient RO/FT 0.75 0.7 Mean 0.6 Air 1.0 0.9 0.8 0.75 0.7 0.6 25 500 1200 2500 210000 ppm level Nitrogen FT RO Figure 1. Main effects plot for PTH on a 0.125”-thick PCB with alcohol flux. Ursula Marquez de Tino is a process and research engineer for Vitronics Soltec (vitronics.com); umarquez@ vitronics-soltec.com. pins and 100% tin matte finish, and 25 axial resistors with 100% tin finish. For all PTH components, except DIPs, the leads were mechanically trimmed to achieve lead protrusions of approximately 0.140". The flux and solder alloy were resin alcohol base noclean flux with 7% solids content and SAC 305, respectively. Boards were subjected to two Pb-free reflow profiles based on the paste manufacturer’s specifications. The results and data analysis provide some intuitive and surprising conclusions. For most types of mid- to high-level complexity employment of a soldering atmosphere where the delivery method is reflow only and atmosphere purity is 2500 ppm, an O2 soldering atmosphere will yield acceptable joints per IPC Class 3. In these cases, the through-hole penetration observed was just under 100%, but clearly visible while viewing the board. For “simple” boards, air atmosphere is suitable. The impact of delivery method was minimal at best, which was the surprising result (Figure 1). Use of high purity atmospheres in the early part of the reflow process exerts a minor effect on through-hole penetration for those simple- to mid-level complexity boards. While flux was not the focus of the experiment, flux did exert a significant effect and may influence desired results. In conclusion, this work sheds light on nitrogen use and its impact on solder joint formation. When developing a soldering process, whether to use nitrogen depends on the materials selected, especially flux, board complexity, and defect definition and characterization. Characterizing the relationship between atmosphere purity, delivery method, nitrogen consumption and preventive maintenance is also important to completely determine atmosphere’s impact on solder joint formation. ■ 62 circuitsassembly.com http://www.vitronics-soltec.com http://www.vitronics-soltec.com http://circuitsassembly.com
Table of Contents Feed for the Digital Edition of Circuits Assembly - March 2008 Circuits Assembly - March 2008 Caveat Lector Letters Industry News Market Watch Talking Heads Focus on Business On the Forefront Screen Printing What Drives the Crowd? Mastering ESD Control in Automated Handling Systems Beating the RoHS Heat Trade Secrets True to Its Roots The Road Abroad - Strategic Alliance or Greenfield Facility? Tech Tips Wave Soldering Test and Inspection Process Doctor Pb-Free Lessons Learned Getting Lean Materials World Equipment Advances Apex Product Preview Ad Index Assembly Insider Technical Abstracts Circuits Assembly - March 2008 Circuits Assembly - March 2008 - Circuits Assembly - March 2008 (Page Cover1) Circuits Assembly - March 2008 - Circuits Assembly - March 2008 (Page Cover2) Circuits Assembly - March 2008 - Circuits Assembly - March 2008 (Page 1) Circuits Assembly - March 2008 - Circuits Assembly - March 2008 (Page 2) Circuits Assembly - March 2008 - Circuits Assembly - March 2008 (Page 3) Circuits Assembly - March 2008 - Circuits Assembly - March 2008 (Page 4) Circuits Assembly - March 2008 - Circuits Assembly - March 2008 (Page 5) Circuits Assembly - March 2008 - Caveat Lector (Page 6) Circuits Assembly - March 2008 - Caveat Lector (Page 7) Circuits Assembly - March 2008 - Letters (Page 8) Circuits Assembly - March 2008 - Letters (Page 9) Circuits Assembly - March 2008 - Industry News (Page 10) Circuits Assembly - March 2008 - Industry News (Page 11) Circuits Assembly - March 2008 - Industry News (Page 12) Circuits Assembly - March 2008 - Industry News (Page 13) Circuits Assembly - March 2008 - Industry News (Page 14) Circuits Assembly - March 2008 - Industry News (Page 15) Circuits Assembly - March 2008 - Industry News (Page 16) Circuits Assembly - March 2008 - Industry News (Page BEST1) Circuits Assembly - March 2008 - Industry News (Page BEST2) Circuits Assembly - March 2008 - Market Watch (Page 17) Circuits Assembly - March 2008 - Talking Heads (Page 18) Circuits Assembly - March 2008 - Talking Heads (Page 19) Circuits Assembly - March 2008 - Focus on Business (Page 20) Circuits Assembly - March 2008 - Focus on Business (Page 21) Circuits Assembly - March 2008 - On the Forefront (Page 22) Circuits Assembly - March 2008 - On the Forefront (Page 23) Circuits Assembly - March 2008 - Screen Printing (Page 24) Circuits Assembly - March 2008 - Screen Printing (Page 25) Circuits Assembly - March 2008 - What Drives the Crowd? (Page 26) Circuits Assembly - March 2008 - What Drives the Crowd? (Page 27) Circuits Assembly - March 2008 - What Drives the Crowd? (Page 28) Circuits Assembly - March 2008 - What Drives the Crowd? (Page 29) Circuits Assembly - March 2008 - Mastering ESD Control in Automated Handling Systems (Page 30) Circuits Assembly - March 2008 - Mastering ESD Control in Automated Handling Systems (Page 31) Circuits Assembly - March 2008 - Mastering ESD Control in Automated Handling Systems (Page 32) Circuits Assembly - March 2008 - Mastering ESD Control in Automated Handling Systems (Page 33) Circuits Assembly - March 2008 - Mastering ESD Control in Automated Handling Systems (Page 34) Circuits Assembly - March 2008 - Mastering ESD Control in Automated Handling Systems (Page 35) Circuits Assembly - March 2008 - Mastering ESD Control in Automated Handling Systems (Page 36) Circuits Assembly - March 2008 - Mastering ESD Control in Automated Handling Systems (Page 37) Circuits Assembly - March 2008 - Beating the RoHS Heat (Page 38) Circuits Assembly - March 2008 - Beating the RoHS Heat (Page 39) Circuits Assembly - March 2008 - Beating the RoHS Heat (Page 40) Circuits Assembly - March 2008 - Beating the RoHS Heat (Page 41) Circuits Assembly - March 2008 - Beating the RoHS Heat (Page 42) Circuits Assembly - March 2008 - Beating the RoHS Heat (Page 43) Circuits Assembly - March 2008 - Beating the RoHS Heat (Page 44) Circuits Assembly - March 2008 - Beating the RoHS Heat (Page 45) Circuits Assembly - March 2008 - Beating the RoHS Heat (Page 46) Circuits Assembly - March 2008 - Beating the RoHS Heat (Page 47) Circuits Assembly - March 2008 - Trade Secrets (Page 48) Circuits Assembly - March 2008 - Trade Secrets (Page 49) Circuits Assembly - March 2008 - Trade Secrets (Page 50) Circuits Assembly - March 2008 - Trade Secrets (Page 51) Circuits Assembly - March 2008 - True to Its Roots (Page 52) Circuits Assembly - March 2008 - True to Its Roots (Page 53) Circuits Assembly - March 2008 - True to Its Roots (Page 54) Circuits Assembly - March 2008 - True to Its Roots (Page 55) Circuits Assembly - March 2008 - The Road Abroad - Strategic Alliance or Greenfield Facility? (Page 56) Circuits Assembly - March 2008 - The Road Abroad - Strategic Alliance or Greenfield Facility? (Page 57) Circuits Assembly - March 2008 - The Road Abroad - Strategic Alliance or Greenfield Facility? (Page 58) Circuits Assembly - March 2008 - The Road Abroad - Strategic Alliance or Greenfield Facility? (Page 59) Circuits Assembly - March 2008 - Tech Tips (Page 60) Circuits Assembly - March 2008 - Tech Tips (Page 61) Circuits Assembly - March 2008 - Wave Soldering (Page 62) Circuits Assembly - March 2008 - Wave Soldering (Page 63) Circuits Assembly - March 2008 - Test and Inspection (Page 64) Circuits Assembly - March 2008 - Test and Inspection (Page 65) Circuits Assembly - March 2008 - Process Doctor (Page 66) Circuits Assembly - March 2008 - Pb-Free Lessons Learned (Page 67) Circuits Assembly - March 2008 - Getting Lean (Page 68) Circuits Assembly - March 2008 - Materials World (Page 69) Circuits Assembly - March 2008 - Equipment Advances (Page 70) Circuits Assembly - March 2008 - Equipment Advances (Page 71) Circuits Assembly - March 2008 - Apex Product Preview (Page 72) Circuits Assembly - March 2008 - Apex Product Preview (Page 73) Circuits Assembly - March 2008 - Apex Product Preview (Page 74) Circuits Assembly - March 2008 - Apex Product Preview (Page 75) Circuits Assembly - March 2008 - Apex Product Preview (Page 76) Circuits Assembly - March 2008 - Apex Product Preview (Page 77) Circuits Assembly - March 2008 - Ad Index (Page 78) Circuits Assembly - March 2008 - Assembly Insider (Page 79) Circuits Assembly - March 2008 - Technical Abstracts (Page 80) Circuits Assembly - March 2008 - Technical Abstracts (Page Cover3) Circuits Assembly - March 2008 - Technical Abstracts (Page Cover4)
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