Circuits Assembly - October 2008 - (Page 20) Better Manufacturing To the Finish For Pb-free PWB surface finishes, there's no panacea, just choices. ne aspect of the Pb-free conversion process is the PWB surface finish. With regard to production volumes, the contenders are HASL, pure tin, NiAu, OSP and immersion silver. There are others and others will evolve no doubt, but at this point, these are the mainstream. 1 Most practitioners shy away from pure tin finishes (matte tin, bright tin and others). It seems the greater the “presence” of tin, the more opportunity and resulting propensity for Snwhisker propagation. While most Pb-free passives are finished in matte tin, these comprise a small aggregate volume of pure tin present in most assemblies compared to assemblies with a pure tin surface finish. Thus, for most products, pure tin would not be the first choice (or second, or third, etc.). Then there is good ol’ hot air solder leveling (HASL). Yes, it is “old”: HASL came about in the mid ’70s and was quickly adapted as “the way” to finish through-hole PCBs with a SnPb coating. Compared to hydro-squeegee, IR SnPb fusing and some other methodologies, HASL was economical, efficient and proficient. HASL was adaptable for early SMT, too. But when component lead pitches started falling below 0.025", HASL presented a hassle. In the HASL process, the PWB is immersed in a bath of molten solder and then squeeged (leveled) with hot air knives. This results in a board surface that, while flatter than reflowed SnPb, is less flat than the immersion coatings. (The vertical machines also left excessive thickness toward the board bottom, an issue horizontal machines remedied). Surface mount requires even topography of the PCB surface. There are strict specifications with regard to the coplanarity of SMT IC leads, but what happens when the pad surfaces those nice coplanar leads are being attached to are inconsistent? The problem is compounded when HASL is accomplished with Pb-free alloys. One, with the higher temperatures (a preheat of 190-200°C, a solder bath of 230°-250°C and air knives operating at 435°-535°C) involved with said alloys, there is a higher probability of PCB warpage. Warpage presents problems in the printing process if there is poor contact between the stencil and board. Besides fine-pitch leaded IC packages, area arrays and QFN packages are also somewhat finicky with regard to PWB topography. 1. For prototype and low-volume situations, the SIPAD process should be given due consideration. O Phil Zarrow is president and a principal consultant at ITM Consulting (itmconsulting. org); phil_zarrow@ itmconsulting.org. Pre-RoHS, HASL made up some 75% of the market. Some assemblers transitioned from HASL long before Pb-free, however, particularly those building PCMCIA cards and other thin substrates. HASL is a known process, one that can be controlled with reasonable effort (with regard to avoiding excessive intermetallic formation, delamination and exposed copper situations), and many fabricators are equipped with the required machinery. A 2006 survey by European Pb-free Soldering Network TUB found approximately 27% of the Pb-free surface finishes used in Europe are HASL. They include SnAgCu, SnNiCu, SnZnCu and a large amount of tin HASL (ugh!). HASL definitely has its fans, but for many, there are better, more coplanar ways to go. ENIG. Early SMT emigrants from HASL adapted gold as surface finish – particularly electroless nickel immersion gold (ENIG) and immersion gold (ImAu). ENIG, with a nickel barrier thickness of 50-150 µin under 3-10 µin of gold, presents uniform thickness and planarity. It also maintains great wettability, even under long storage conditions, and good surface contact for ICT. Sounds rather idyllic. To its detriment, gold is expensive. (Then again, what isn’t, except maybe lead?) Apparently, controlling the plating process(es) is also a bit more demanding, as is evident by the number of fabricators that do not consistently exercise such control. Black pad, whether resulting from excessive nickel corrosion, insufficient gold (as discussed in a previous column), or improper phosphorous content of the nickel (it should be a 7-12% maximum codeposit) resulting in poor gold adhesion, rewards the assembler with weak joints or even outright opens. Embrittlement results from excessive gold deposits (more than 30 µin) with grainy appearance and poor joint strength. In fact, poor joint strength has been a concern in applications that experience shock, particularly where area arrays are soldered. We seldom see NiAu finishes in cellphones and PDAs anymore. Weak joints are somewhat systematic because the SnNi intermetallic does not form as rapidly as does SnCu. This is why many handheld devices do not use ENIG. Remember, ENIG is the only surface finish where the soldering is to nickel, not copper. OSPs. Organic solder protectants have improved greatly during the past decade and have seen circuitsassembly.com 20 Circuits Assembly OCTOBER 2008 http://itmconsulting.org http://itmconsulting.org http://www.circuitsassembly.com
Table of Contents Feed for the Digital Edition of Circuits Assembly - October 2008 Circuits Assembly - September 2008 Contents Letters Caveat Lector Industry News Market Watch Talking Heads Global Sourcing Screen Printing Better Manufacturing 'Checking Up' on Medical Electronics Solder Ball Attachment Using Laser Soldering Improving QFN Reliability Reflow Soldering Tech Tips Test and Inspection Process Doctor Pb-Free Lessons Learned Alternative Energies Eastern Advances Product Spotlight Ad Index Assembly Insider Technical Abstracts Circuits Assembly - October 2008 Circuits Assembly - October 2008 - Circuits Assembly - September 2008 (Page Cover1) Circuits Assembly - October 2008 - Circuits Assembly - September 2008 (Page Cover2) Circuits Assembly - October 2008 - Circuits Assembly - September 2008 (Page 1) Circuits Assembly - October 2008 - Circuits Assembly - September 2008 (Page 2) Circuits Assembly - October 2008 - Contents (Page 3) Circuits Assembly - October 2008 - Letters (Page 4) Circuits Assembly - October 2008 - Letters (Page 5) Circuits Assembly - October 2008 - Caveat Lector (Page 6) Circuits Assembly - October 2008 - Caveat Lector (Page 7) Circuits Assembly - October 2008 - Industry News (Page 8) Circuits Assembly - October 2008 - Industry News (Page 9) Circuits Assembly - October 2008 - Industry News (Page 10) Circuits Assembly - October 2008 - Industry News (Page 11) Circuits Assembly - October 2008 - Industry News (Page 12) Circuits Assembly - October 2008 - Industry News (Page 13) Circuits Assembly - October 2008 - Market Watch (Page 14) Circuits Assembly - October 2008 - Market Watch (Page 15) Circuits Assembly - October 2008 - Talking Heads (Page 16) Circuits Assembly - October 2008 - Talking Heads (Page best1) Circuits Assembly - October 2008 - Talking Heads (Page best2) Circuits Assembly - October 2008 - Global Sourcing (Page 17) Circuits Assembly - October 2008 - Screen Printing (Page 18) Circuits Assembly - October 2008 - Screen Printing (Page 19) Circuits Assembly - October 2008 - Better Manufacturing (Page 20) Circuits Assembly - October 2008 - Better Manufacturing (Page 21) Circuits Assembly - October 2008 - Better Manufacturing (Page 22) Circuits Assembly - October 2008 - Better Manufacturing (Page 23) Circuits Assembly - October 2008 - 'Checking Up' on Medical Electronics (Page 24) Circuits Assembly - October 2008 - 'Checking Up' on Medical Electronics (Page 25) Circuits Assembly - October 2008 - 'Checking Up' on Medical Electronics (Page 26) Circuits Assembly - October 2008 - 'Checking Up' on Medical Electronics (Page 27) Circuits Assembly - October 2008 - Solder Ball Attachment Using Laser Soldering (Page 28) Circuits Assembly - October 2008 - Solder Ball Attachment Using Laser Soldering (Page 29) Circuits Assembly - October 2008 - Solder Ball Attachment Using Laser Soldering (Page 30) Circuits Assembly - October 2008 - Solder Ball Attachment Using Laser Soldering (Page 31) Circuits Assembly - October 2008 - Improving QFN Reliability (Page 32) Circuits Assembly - October 2008 - Improving QFN Reliability (Page 33) Circuits Assembly - October 2008 - Reflow Soldering (Page 34) Circuits Assembly - October 2008 - Tech Tips (Page 35) Circuits Assembly - October 2008 - Test and Inspection (Page 36) Circuits Assembly - October 2008 - Test and Inspection (Page 37) Circuits Assembly - October 2008 - Process Doctor (Page 38) Circuits Assembly - October 2008 - Pb-Free Lessons Learned (Page 39) Circuits Assembly - October 2008 - Alternative Energies (Page 40) Circuits Assembly - October 2008 - Alternative Energies (Page 41) Circuits Assembly - October 2008 - Eastern Advances (Page 42) Circuits Assembly - October 2008 - Eastern Advances (Page 43) Circuits Assembly - October 2008 - Product Spotlight (Page 44) Circuits Assembly - October 2008 - Product Spotlight (Page 45) Circuits Assembly - October 2008 - Ad Index (Page 46) Circuits Assembly - October 2008 - Assembly Insider (Page 47) Circuits Assembly - October 2008 - Technical Abstracts (Page 48) Circuits Assembly - October 2008 - Technical Abstracts (Page Cover3) Circuits Assembly - October 2008 - Technical Abstracts (Page Cover4)
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